The magnetic structure of the quadruple perovskite SrCu3Fe4O12 is studied by means of neutron powder diffraction. The magnetic diffraction peaks are observed at low temperatures below 200 K. The Rietveld refinement result suggests an antiferromagnetic alignment of Fe spin magnetic moments for SrCu3Fe4O12 at low temperature. The refined magnetic moment at 4 K is ∼3.5 µB, which is larger than that of that of CeCu3Fe4O12 (2.3 µB). The increase in the magnetic moment is attributed to the larger Fe3+:Fe5+ ratio for SrCu3Fe4O12 (∼4:1) compared with that of CeCu3Fe4O12 (∼3:1).

1.
A. P.
Ramirez
,
M. A.
Subramanian
,
M.
Gardel
,
G.
Blumberg
,
D.
Li
,
T.
Vogt
and
S. M.
Shapiro
,
Solid State Commun.
115
,
217
220
(
2000
).
2.
M. A.
Subramanian
,
D.
Li
,
N.
Duan
,
B. A.
Reisner
and
A. W.
Sleight
,
J. Solid State Chem.
151
,
323
325
(
2000
).
3.
Z.
Zeng
,
M.
Greenblatt
,
M. A.
Subramanian
and
M.
Croft
,
Phys. Rev. Lett.
82
,
3164
3167
(
1999
).
4.
J. A.
Alonso
,
J.
Sanchez-Benitez
,
A.
De Andres
,
M. J.
Martinez-Lope
,
M. T.
Casais
and
J. L.
Martinez
,
Appl. Phys. Lett.
83
,
2623
2625
(
2003
).
5.
W.
Kobayashi
,
I.
Terasaki
,
J.-i.
Takeya
,
I.
Tsukada
and
Y.
Ando
,
J. Phys. Soc. Jpn.
73
,
2373
2376
(
2004
).
6.
I.
Yamada
,
K.
Tsuchida
,
K.
Ohgushi
,
N.
Hayashi
,
J.
Kim
,
N.
Tsuji
,
R.
Takahashi
,
M.
Matsushita
,
N.
Nishiyama
,
T.
Inoue
,
T.
Irifune
,
K.
Kato
,
M.
Takata
and
M.
Takano
,
Angew. Chem. Int. Ed.
50
,
6579
6582
(
2011
).
7.
B.
Bochu
,
J.
Chenavas
,
J. C.
Joubert
and
M.
Marezio
,
J. Solid State Chem.
11
,
88
93
(
1974
).
8.
J.
Chenavas
,
J. C.
Joubert
,
M.
Marezio
and
B.
Bochu
,
J. Solid State Chem.
14
,
25
32
(
1975
).
9.
I.
Yamada
,
K.
Takata
,
N.
Hayashi
,
S.
Shinohara
,
M.
Azuma
,
S.
Mori
,
S.
Muranaka
,
Y.
Shimakawa
and
M.
Takano
,
Angew. Chem. Int. Ed.
47
,
7032
7035
(
2008
).
10.
Y. W.
Long
,
N.
Hayashi
,
T.
Saito
,
M.
Azuma
,
S.
Muranaka
and
Y.
Shimakawa
,
Nature
458
,
60
63
(
2009
).
11.
I.
Yamada
,
K.
Shiro
,
K.
Oka
,
M.
Azuma
and
T.
Irifune
,
J. Ceram. Soc. Jpn.
121
,
912
914
(
2013
).
12.
M.
Mizumaki
,
W. T.
Chen
,
T.
Saito
,
I.
Yamada
,
J. P.
Attfield
and
Y.
Shimakawa
,
Phys. Rev. B
84
,
094418
(
2011
).
13.
F.
Izumi
and
K.
Momma
,
Solid State Phenom.
130
,
15
20
(
2007
).
14.
W.
Chen
,
Y. W.
Long
,
T.
Saito
,
J. P.
Attfield
and
Y.
Shimakawa
,
J. Mater. Chem.
20
,
7282
7286
(
2010
).
15.
I.
Yamada
,
H.
Etani
,
M.
Murakami
,
N.
Hayashi
,
T.
Kawakami
,
M.
Mizumaki
,
S.
Ueda
,
H.
Abe
,
K.-D.
Liss
,
A. J.
Studer
,
T.
Ozaki
,
S.
Mori
,
R.
Takahashi
and
T.
Irifune
,
Inorg. Chem.
53
,
11794
11801
(
2014
).
16.
I.
Yamada
,
K.
Shiro
,
H.
Etani
,
S.
Marukawa
,
N.
Hayashi
,
M.
Mizumaki
,
Y.
Kusano
,
S.
Ueda
,
H.
Abe
and
T.
Irifune
,
Inorg. Chem.
53
,
10563
10569
(
2014
).
This content is only available via PDF.
You do not currently have access to this content.