Single-phase polycrystalline samples of Bi0.8Nd0.2−xCaxFeO3 (x = 0.0, 0.1) were synthesized by chemical coprecipitation method. X-ray diffraction patterns accompanied by Rietveld-refined crystal structure parameters reveal the phase transition of Bi0.8Nd0.1Ca0.1FeO3 with rhombohedral R3c symmetry to triclinic structure of Bi0.8Nd0.2FeO3 sample. Frequency dependence of dielectric constant (ε') and dielectric loss (tanδ), infers enhancement of both ε' (tanδ) in narrow band gap of Nd/Ca co-doped BFO as compare to wide band pristine BFO.

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