As a non‐contact, in‐line monitoring technique for stress/strain and crystallinity of Si, epitaxial Si1−xGex/Si and implanted Si, a polychromator‐based, high resolution, multi‐wavelength Raman spectroscopy system was evaluated. Three major spectral lines at 457.9, 488.0 and 514.5 nm from a multi‐wavelength Ar ion laser were used as the excitation source for virtual depth profiling of material properties. Si stress/strain and Ge content were accurately measured from ultra thin (>5 nm) epitaxial Si1−xGex/Si. Crystalline stress value of C‐implanted Si and stress change before and after annealing were also successfully characterized. High resolution, multi‐wavelength μ‐Raman spectroscopy is shown to be a very promising non‐contact, in‐line characterization technique for nanoelectronic materials.

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