Ultra‐shallow boron implanted (B+ 1 keV 1×1015cm−2) n‐type Si wafers were prepared and characterized by four point probe, SIMS and 363.8 nm excited ultra‐violet (UV) Raman spectroscopy before and after rapid thermal annealing (RTA). The penetration depth of 363.8 nm laser radiation in a backscattering Raman configuration, is approximately 5 nm. As junction depth increases from high temperature RTA, sheet resistance decreases. Raman peaks shift in the lower wavenumber direction and its full‐width‐at‐half‐maximum (FWHM) broadens. There is clear correlation between junction depth and Raman spectra data. UV Raman spectroscopy can be used as a very powerful non‐contact, non‐destructive, in‐line characterization and monitoring technique for ultra‐shallow junctions (USJs).

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