We present a high‐accuracy calculation of the π̄d scattering length using chiral perturbation theory up to order (Mπ/mp)7/2. For the first time isospin‐violating corrections are included consistently. The resulting value of aπ̄d has a theoretical uncertainty of a few percent. We use it, together with data on pionic deuterium and pionic hydrogen atoms, to extract the isoscalar and isovector pion‐nucleon scattering lengths from a combined analysis, and obtain a+ = (7.9±3.2)⋅10−3Mπ−1 and ā = (86.3±1.0)⋅10−3Mπ−1.

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