We develop a series solution for the bound-state energy levels of the quantum-mechanical one-dimensional finite square-well potential. We show that this general solution is useful for local approximations of the energy spectrum (which target a particular energy range of the potential well for high accuracy), for global approximations of the energy spectrum (which provide analytic expressions of reasonable accuracy for the entire range of bound states), and for numerical methods. This solution also provides an analytic description of dynamical phenomena; with it, we compute the time scales of classical motion, revivals, and super-revivals for wave-packet states excited in the well.
REFERENCES
1.
C. D.
Cantrell
, “Bound-state energies of a particle in a finite square well: An improved graphical solution
,” Am. J. Phys.
39
, 107
–110
(1971
).2.
S. Gasiorowicz, Quantum Physics (Wiley, New York, 1996), 2nd ed., pp. 78–83.
3.
D. J. Griffiths, Introduction to Quantum Mechanics (Prentice–Hall, Englewood Cliffs, NJ, 1995), pp. 60–66.
4.
R. L. Liboff, Introductory Quantum Mechanics (Addison–Wesley, Reading, MA, 1992), 2nd ed., pp. 275–284.
5.
H. C. Ohanian, Principles of Quantum Mechanics (Prentice–Hall, Englewood Cliffs, NJ, 1990), pp. 78–84.
6.
For an introductory discussion of wave-packet dynamics in the hydrogen atom and its connections to classical mechanics, see
M.
Nauenberg
, C. R.
Stroud
, Jr., and J.
Yeazell
, “The classical limit of an atom
,” Sci. Am.
270
, 24
–29
(June 1994
).7.
J.
Parker
and C. R.
Stroud
, Jr., “Coherence and decay of Rydberg wave packets
,” Phys. Rev. Lett.
56
, 716
(1986
).8.
M.
Nauenberg
, “Autocorrelation function and quantum recurrence of wavepackets
,” J. Phys. B
23
, L385
–L390
(1990
).9.
R.
Bluhm
, V. A.
Kostelecký
, and J. A.
Porter
, “The evolution and revival structure of localized quantum wave packets
,” Am. J. Phys.
64
, 944
–953
(1996
).10.
Z. D.
Gaeta
and C. R.
Stroud
, Jr., “Classical and quantum-mechanical dynamics of a quasi-classical state of the hydrogen atom
,” Phys. Rev. A
42
, 6308
–6313
(1990
).11.
D. L.
Aronstein
and C. R.
Stroud
, Jr., “Fractional wave-function revivals in the infinite square well
,” Phys. Rev. A
55
, 4526
–4537
(1997
).12.
B. I.
Barker
, G. H.
Rayborn
, J. W.
Ioup
, and G. E.
Ioup
, “Approximating the finite square well with an infinite well: Energies and eigenfunctions
,” Am. J. Phys.
59
, 1038
–1042
(1991
).13.
L. I. Schiff, Quantum Mechanics (McGraw–Hill, New York, 1968), 3rd ed., pp. 37–44.
14.
P. H.
Pitkanen
, “Rectangular potential well problem in quantum mechanics
,” Am. J. Phys.
23
, 111
–113
(1955
).15.
P. G.
Guest
, “Graphical solutions for the square well
,” Am. J. Phys.
40
, 1175
–1176
(1972
).16.
R. D.
Murphy
and J. M.
Phillips
, “Bound-state eigenvalues of the square-well potential
,” Am. J. Phys.
44
, 574
–576
(1976
).17.
W. C.
Elmore
, “Eigenvalues of the square-well problem
,” Am. J. Phys.
39
, 976
–977
(1971
).18.
E. J.
Burge
, “Improved simple graphical solution for the eigenvalues of the finite square well potential
,” Eur. J. Phys.
6
, 154
–164
(1985
).19.
B. C.
Reed
, “A single equation for finite rectangular well energy eigenvalues
,” Am. J. Phys.
58
, 503
–504
(1990
).We note that Pitkanen (Ref. 14) mentioned the possibility of such a unified equation, without developing it analytically, some 35 years earlier.
20.
D. W. L.
Sprung
, H.
Wu
, and J.
Martorell
, “A new look at the square well potential
,” Eur. J. Phys.
13
, 21
–25
(1992
).21.
P. M. Morse and H. Feshbach, Methods of Theoretical Physics (McGraw–Hill, New York, 1953), Vol. 1, pp. 411–413.
22.
M. Abramowitz and I. A. Stegun, Handbook of Mathematical Functions (Dover, New York, 1972), p. 16.
23.
D. W. L.
Sprung
, H.
Wu
, and J.
Martorell
, “Poles, bound states, and resonances illustrated by the square well potential
,” Am. J. Phys.
64
, 136
–144
(1996
).24.
W. H. Press, S. A. Teukolsky, W. T. Vetterling, and B. P. Flannery, Numerical Recipes: The Art of Scientific Computing (Cambridge U.P., Cambridge, 1992), 2nd ed., Sec. 9.4.
Note also that numerical iteration methods for finding energy levels are discussed in detail by Murphy and Phillips (Ref. 16).
25.
C.
Leichtle
, I. Sh.
Averbukh
, and W. P.
Schleich
, “Multilevel quantum beats: An analytical approach
,” Phys. Rev. A
54
, 5299
–5312
(1996
).26.
A.
Venugopalan
and G. S.
Agarwal
, “Superrevivals in the quantum dynamics of a particle confined in a finite square-well potential
,” Phys. Rev. A
59
, 1413
–1422
(1999
).27.
D. L.
Aronstein
and C. R.
Stroud, Jr.
, “Analytical investigation of revival phenomena in the finite square-well potential
,” Phys. Rev. A
62
, 022102
(2000
).28.
The first wave-packet revival occurs in the vicinity of time but the exact moment when the re-formed packet passes through its original location is a (known) function of both and Similarly, the details of super-revival phenomena depend on and This is discussed on
O.
Knospe
and R.
Schmidt
, “Revivals of wave packets: General theory and applications to Rydberg clusters
,” Phys. Rev. A
54
, 1154
–1160
(1996
).29.
R.
Bluhm
and V. A.
Kostelecký
, “Long-term evolution and revival structure of Rydberg wave packets
,” Phys. Lett. A
200
, 308
–313
(1995
).
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